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On Thu, 20 Jan 2005 19:40:45 GMT, Joe Riel
wrote: writes: Any idea what "some problem" might be? Is petroleum supposed to cause butyl inner tubes to dissolve, grow brittle, ignite in spontaneous combustion, discolor, shrink, expand, smell terrible, foul Presta valves, crack at their seams, glue themselves to the tire casing, cause valve stems to fall out, or what? It appears to affect the tensile strength. A relevant document is ASTM D 471 "STANDARD TEST METHOD FOR RUBBER PROPERTY-EFFECT OF LIQUIDS" I can purchase it for $39, however, I suspect that the local university has a copy. Can anyone out there summarizee the relevant sections? From another document (EM 1110-1-4008) I found the following info: In addition, standards for resistance to oil and gasoline exposure have been developed by the Rubber Manufacturer's Association (RMA). These standards are related to the effects of oil or gasoline exposure for 70 hours at 100C (ASTM D 471) on the physical/mechanical properties of the material. Table 6-4 summarizes the requirements of the RMA oil and gasoline resistance classes. Table 6-4 RMA Oil and Gasoline Resistance Classifications RMA Designation Tensile Strength Retained Class A (High oil resistance) 80% Class B (Medium-High oil resistance) 50% Class C (Medium oil resistance) 40% Source: RMA, "The 1996 Hose Handbook," IP-2, p.52 Note that Isobutylene Isoprene, which is, I believe, the rubber used in inner tubes, is classified as having poor oil resistance. Presumably, then, its tensile strength is reduced by more than 60%; how much more I have no idea. Joe Dear Joe, So oil reduces the tensile strength of inner tube. Hmmm . . . But how much does tensile strength matter in an inner tube, which is expands only slightly before being flattened against the inside of the rim and tire? That is, the inner tube isn't under much tension, just a slight expansion before it suffers much higher compression against the inside of the tire and rim. This paradox might explain why some people are saying that there's no problem, while others are saying that oil is bad for butyl rubber. Thanks for finding what actually happens. Carl Fogel |
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#33
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Joe Riel wrote:
writes: Any idea what "some problem" might be? Is petroleum supposed to cause butyl inner tubes to dissolve, grow brittle, ignite in spontaneous combustion, discolor, shrink, expand, smell terrible, foul Presta valves, crack at their seams, glue themselves to the tire casing, cause valve stems to fall out, or what? It appears to affect the tensile strength. A relevant document is ASTM D 471 "STANDARD TEST METHOD FOR RUBBER PROPERTY-EFFECT OF LIQUIDS" I can purchase it for $39, however, I suspect that the local university has a copy. Can anyone out there summarizee the relevant sections?... If this standard is written like other ASTM standards, it will tell you how to run the test, but will not provide any information about typical results. -- Tom Sherman - Near Rock Island |
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Joe Riel writes:
So, how much smaller should the small diameter of a tube be, compared to the inner diameter of a tire, so that, when fully inflated, the hoop stress in the tube is zero? You have 10 minutes... Pencils down. Assume the major diameter of the tube matches that of the tire. Rubber is essentially incompressible, so the flattening due to compression must match the minor diameter increase to achieve a zero hoop stress. The elasticity of butyl rubber is about 600psi (4.5MPa). A tire pumped to 105 psig has an absolute pressure of 105psi + 15psi = 120psi. So the rubber compression is 120/600 = 20%. The initial diameter of the inner tube should be 20% less than the inner diameter of the tire, assuming the final cross sectional shape is circular, only a fair approximation for a clincher, but pretty good for a tubular. Joe |
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